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Title: |
Syngas Generation from Hydrocarbons & Oxygenates with Structured Catalysts |
Search Result:
| By (author): |
Vladislav Sadykov, L Bobrova, S Pavlova, V Simagina, L Makarshin, V Parmon, Julian R H Ross, Claude Mirodatos |
| ISBN10-13: |
1608763234 : 9781608763238 |
| Format: |
Paperback |
| Size: |
155x230mm |
| Pages: |
140 |
| Weight: |
.228 Kg. |
| Published: |
Nova Science Publishers, Inc (US) - July 2012 |
| List Price: |
52.99 Pounds Sterling |
| Availability: |
Temporarily Out of Stock, more expected soon
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| Subjects: |
Energy technology & engineering |
| Syngas generation by oxidative or steam reforming of hydrocarbons and oxygenates now attracts a lot of attention of researchers in the fields of heterogeneous catalysis and chemical engineering due to its tremendous importance for energy generation and synfuels production. This book reviews results of the long-term research of the international team of scientists aimed at development of efficient processes of syngas generation in structured catalytic reactors. Multiscale integrated optimisation approach is applied throughout of this work including design of nanocomposite active components stable to coking and sintering; developing heat-conducting monolithic substrates comprised of refractory alloys and cermets (honeycomb and microchannel structures, gauzes etc) and procedures of their loading with active components; design and manufacturing of several types of pilot-scale reactors (with the radial or the axial flow direction) equipped with unique liquid fuel evaporation and mixing units and internal heat exchangers. Extended tests of these reactors fed by fuels from C1 to gasoline, mineral and sunflower oil have been carried out with a broad variation of experimental parameters including stability tests up to 1000 h. Performance analysis has been made with a due regard for equilibrium restrictions on the operational parameters. Transient behaviour of the monolith reactor during start-up (ignition) of the methane partial oxidation to synthesis gas was studied and analysed via mathematical modelling based upon detailed elementary step mechanism. This provides required bases for theoretical optimisation of the catalyst bed configuration and process parameters. |
| Table of Contents: |
| Preface; Introduction; Reforming chemistry; Catalysts for reforming hydrocarbon fuels & oxygenates; Thermodynamics of fuels reforming into syngas; Numerical study of the partial oxidation of methane; Some application of structured catalysts for syngas generation from hydrocarbons & oxygenates in the pilot scale reactors; Unbidden phenomena in the reforming reactor; Conclusion; Index. |
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